Viologen photooxidation of thiacarbocyanine dyes and their supramolecular complexes with cucurbit[8]uril

G. V. Zakharova; Захарова Г. В.; T. V. Fedotova; Федотова Т. В.; A. K. Chibisov; Чибисов А. К.

doi:10.31857/S0023119324050053

Viologen photooxidation of thiacarbocyanine dyes and their supramolecular complexes with cucurbit[8]uril

Authors: Zakharova G.V.¹, Fedotova T.V.¹, Chibisov A.K.¹
Affiliations:
1. “Kurchatov Institute” National Research Center
Issue: Vol 58, No 5 (2024)
Pages: 379-384
Section: ФОТОХИМИЯ
URL: https://pediatria.orscience.ru/0023-1193/article/view/684844
DOI: https://doi.org/10.31857/S0023119324050053
EDN: https://elibrary.ru/TXUVIA
ID: 684844

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
Full Text
About the authors
References
Supplementary files
Statistics

Abstract

The photooxidation reaction of 3,3'-diethyl-9–methylthiacarbocyanine and 3,3'-diethylthiacarbocyanine by viologenes (methyl viologenes, p-chlorophenyl viologenes, p-cyanophenyl viologenes) in acetonitrile and their dimeric complexes with cucurbit[8]uril by monomeric complexes of viologenes in presence of cucurbit[8]uril in water has been studied. The products of photooxidation of dye monomers in acetonitrile are dye dication-radicals and cation-radicals of viologens. The photooxidation of dimeric complexes produces trication radicals of dimeric complexes and cation radicals of monomeric complexes of viologens. The most efficient reaction is the photooxidation of dyes in acetonitrile.

Keywords

thiacarbocyanines, viologens, cucurbit[8]uril, supramolecular complexes, delayed fluorescence, phosphorescence, triplet state, photooxidation

Full Text

About the authors

G. V. Zakharova

“Kurchatov Institute” National Research Center

Author for correspondence.
Email: gvzakharova@gmail.com

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Russian Federation, Moscow, 119421

T. V. Fedotova

“Kurchatov Institute” National Research Center

Email: tatyana.fedotova@phystech.edu

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Russian Federation, Moscow, 119421

A. K. Chibisov

“Kurchatov Institute” National Research Center

Email: alexander.chibisov@gmail.com

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Russian Federation, Moscow, 119421

References

James, T.L. The Theory of the Photographic Process, Chemistry, 1980. 672 p.
Kachkovsky A.D. Structure and colour of polymethine dyes, Kiev: Naukova Dumka, 1989. 231 p.
Shapiro, B.I. //Usp. Khim., 2006, vol. 75, p. 484.
Chibisov, A.K., Alfimov, M.V., Zakharova, G.V., Atabekyan, L.S., Avakyan, V.G., and Plotnikov, V.G. // High Energy Chem., 2017, vol. 51, iss. 6, p. 480.
Chibisov, A.K., Alfimov, M.V., Zakharova, G.V. et al. //Izv. Akad. Nauk, Ser. Khim., 2022, no. 2, p. 199.
Chibisov, A.K., Slavnova, T.D., and Görner, H. // Nanotechnol. Russ., 2008, vol. 3, Iss. 1, p. 26.
Fedotova, T.V., Zakharova, G. V., and Chibisov, A.K. // Optics and Spectrum. 2022. V. 130. Iss. 5. P. 675.
Jeon W.S., Kim H-J., Lee C. // Kim K., Chem. Commun. 2002. P. 1829.
Biedermfnn F., Scherman A.J. // Phys. Chem. B. 2012. V. 116. P. 2842.
Atabekyan, L.S., Chibisov A.K. // High Energy Chem., 2007, vol. 41, iss. 5, p. 122.
Alperovich M.A., Lifshitz E.B. // Uspekhi nauchnoi fotografii. (Advances in scientific photogrpahy) 1989. V. 25. P. 51.
Savin V.M., Chibisov A.K. // High Energy Chemistry. 1989. V. 8. Iss. 5. P. 584.

Supplementary files

Supplementary Files

Action

1. JATS XML

Download

2. Fig. 1. Time-resolved differential absorption spectra of Cd1 (1 × 10 – 5 mol/L) in the presence of MV (5 × 10 – 4 mol/l) in acetonitrile. The time of measurement of the spectra is shown in the frame. The insert shows kinetic curves of deactivation of the T-state of Cr1 in the presence of MV at 630 nm (1) and kinetic curves of formation of radical photoreaction products: Cr12+• at 460 nm (2) and MV+• at 390 nm (3).

Download (115KB)

Indexing metadata

3. Fig. 2. Time-resolved difference absorption spectra of Cr12•2CB[8] in the presence of Cl-PV•CB[8]. The time of measurement of the spectra is shown in the frame. The insert shows the kinetic curves of deactivation of the T-state Cr12•2CB[8] (1) in the presence of Cl-PV•CB[8] and the kinetic curve of formation of radical photoreaction products: Cr123+••2CB[8] and Cl-PV+••CB[8] (2). Concentrations: Cr1 – 1 × 10 –5 mol / L, Cl – PV-1 × 10 -5 mol / L, CB[8] – 4 × 10 -5 mol / L.

Download (127KB)

Indexing metadata

4. Fig. 3. Kinetic curves of attenuation of delayed fluorescence of Kr22•2CB[8] in the presence of MV. The insert shows a graphical definition of the quenching rate constant of delayed fluorescence by the MV•CB complex[8]. In the frame is the concentration of MV. The concentration of Cd2 is 1.2 × 10 – 6 mol / l, the concentration of CB[8] is 5 × 10 – 5 mol / L.