Binding of gold(III) using bismuth hexamethylenedithiocarbamate: the double complexes of [Au(S2CNHm)2][Bi(S2CNHm)2Cl2] and [Au(S2CNHm)2]2[Bi2(S2CNHm)2Cl6] (preparation, crystal structure, thermal behavior and anti-mycobacterial activity)
- Authors: Novikova E.V.1, Lutsenko I.A.2,3, Bekker O.B.4, Nelyubina Y.V.5, Ivanov A.V.1
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Affiliations:
- Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Peoples' Friendship University of Russia named after Patrice Lumumba
- Vavilov Institute of General Genetics, Russian Academy of Sciences
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 70, No 4 (2025)
- Pages: 527-541
- Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://pediatria.orscience.ru/0044-457X/article/view/686974
- DOI: https://doi.org/10.31857/S0044457X25040069
- EDN: https://elibrary.ru/HOUVVJ
- ID: 686974
Cite item
Abstract
It was established that during the interaction of bismuth hexamethylenedithiocarbamate (HmDtc) with a H[AuCl4]/2M HCl solution, the individual forms of gold(III) binding in the solid phase are double complexes of [Au(S2CNHm)2][Bi(S2CNHm)2Cl2] (I) and [Au(S2CNHm)2]2[Bi2(S2CNHm)2Cl6] (II). The structures of the obtained compounds include centrosymmetric/non-centrosymmetric (in I/II) complex cations of Au(III), as well as heteroleptic bismuth anions: both the mononuclear and binuclear, whose the ratio Bi : Dtc : Cl = = 1:2:2/2:2:6 (I/II). The secondary S∙∙∙S and S∙∙∙Cl interactions that arise between these ionic structural units lead to the formation of three-dimensional supramolecular architectures. In the IR spectra of the compounds, the absorption bands of N–C(S)S bonds were assigned to HmDtc ligands in the inner sphere of Au(III) complex cations and Bi(III) anions. Thermal behavior of I and II was studied using the STA technique. The residual substance obtained after thermolysis of the samples is represented by metallic particles of a solid solution of bismuth in gold, coated with a layer of Bi2O3. For complex I, a high level of anti-mycobacterial activity in vitro was revealed against the non-pathogenic strain Mycolicibacterium smegmatis.
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About the authors
E. V. Novikova
Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk, 675000
I. A. Lutsenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Peoples' Friendship University of Russia named after Patrice Lumumba
Email: alexander.v.ivanov@chemist.com
Russian Federation, Moscow, 119991; Moscow, 117198
O. B. Bekker
Vavilov Institute of General Genetics, Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
Russian Federation, Moscow, 119333
Yu. V. Nelyubina
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
Russian Federation, Moscow, 119334
A. V. Ivanov
Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences
Author for correspondence.
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk, 675000
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