SURFACE DEGRADATION OF CERAMIC MATERIAL BASED ON THE ZrB2-HfB2-SiC SYSTEM UNDER THE INFLUENCE OF A SUBSONIC FLOW OF DISSOCIATED NITROGEN CONTAINING 5 mol. % CO2

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Resumo

Ultra-high-temperature ceramics based on zirconium and hafnium diborides are of great scientific and technical interest, as they can be very promising, including as components of descent vehicles for space exploration. To study the behavior of these ceramics under the influence of high-speed flows of dissociated gases of complex composition and to determine the effect of modifying the ZrB2-HfB2-SiC system with carbon nanotubes, the process of surface degradation under the influence of a subsonic flow of dissociated nitrogen containing 5 mol. % CO2 was examined. Despite the relatively low CO2 content in the nitrogen plasma, the surface oxidation process dominated the conversion of the initial ZrB2/HfB2 into solid solutions based on monocarbonitrides of these metals. In this case, it was noted that a protective layer of silicate glass does not form on the surface, unlike similar materials under the influence of subsonic flows of dissociated air at temperatures <1750–1800°C.

Sobre autores

E. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

A. Chaplygin

Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences

Email: chaplygin@ipmnet.ru
Moscow, Russia

A. Lysenkov

A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

I. Nagornov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

I. Lukomskii

Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

A. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

N. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

A. Kolesnikov

Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: ep_simonenko@mail.ru
Moscow, Russia

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