Synthesis and Luminescent Properties of the Carbonyl-Isonitrile Re(I) Complex Based on Menthol-Modified Phenanthroline

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Abstract

A carbonyl-isonitrile complex of [Re(CO)₃(L)(m-XylylNC)]OTf formulation (m-XylylNC – 2,6-dimethyl-phenyl isocyanide) was synthesized based on the 1,10-phenanthroline ligand (L) containing a menthol fragment (MtO–) in position 2. The Re(I) atom in the cationic part of this complex has a distorted octahedral environment formed by the N,N′-chelate ligand L, one isonitrile ligand, and three CO ligands. The resulting compound exhibits bright green phosphorescence at room temperature in both the solid state and solution, with quantum yields of 15% and 10%, respectively.

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About the authors

M. P. Davydova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
Russian Federation, Novosibirsk

A. M. Agafontsev

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
Russian Federation, Novosibirsk

V. N. Yudin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
Russian Federation, Novosibirsk

M. I. Rakhmanova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
Russian Federation, Novosibirsk

A. V. Artem’ev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: chemisufarm@yandex.ru
Russian Federation, Novosibirsk

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Supplementary files

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2. Additional materials
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3. Scheme 1. Synthesis of complex I.

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4. Fig. 1. Structure of complex I. The disordered part of the menthol fragment and solvate molecules are not shown.

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5. Fig. 2. Channels in the structure of complex I along the direction [0 1 −1].

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6. Fig. 3. Powder and solution of complex I in daylight and UV light (365 nm) (a); normalized excitation (λem = 510 nm) and PL (λexc = 340 nm) spectra for a solid sample of I (b); normalized absorption, excitation (λem = 525 nm), and PL (λexc = 405 nm) spectra for a solution of I (MeCN, 10⁻⁵ mol/L) (c).

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