A SIMPLE CATALYST FOR THE SYNTHESIS OF CYCLIC CARBONATES BASED ON ZINC(II) IODIDE

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

A new zinc(II) complex, LZnI2, was obtained by the interaction of tridentate ligand 2,6-bis(5-(tert-butyl)-1H-pyrazol-3-yl)pyridine (L) with zinc(II) iodide. The compound was isolated in individual form and characterized using NMR spectroscopy and single-crystal X-ray diffraction (CIF file CCDC No. 2447394). The resulting complex exhibits catalytic activity in the reaction of CO2 with substituted epoxides to form cyclic carbonates. This behavior is attributed to the simultaneous presence of a Lewis acidic metal center capable of coordinating the epoxide, a Lewis basic nitrogen site facilitating CO2 binding, and a nucleophilic iodide anion that activates epoxide ring opening. The development of this approach to catalyst design may facilitate the creation of efficient systems for reactions of carbon dioxide with three-membered heterocycles.

Авторлар туралы

M. Tugushev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; National Research University Higher School of Economics

Email: tugushev.misha07@gmail.com
Senior Laboratory Assistant Moscow, Russian Federation; Moscow, Russian Federation

D. Strunin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Lomonosov Moscow State University

Email: strunin02@yandex.ru
Senior Laboratory Assistant Moscow, Russian Federation; Moscow, Russian Federation

A. Danshina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: danshina.aa@phystech.edu
ORCID iD: 0000-0003-0368-2177
Junior Researcher Moscow, Russian Federation; Moscow, Russian Federation

Yu. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: unelya@ineos.ac.ru
ORCID iD: 0000-0002-9121-0040
Dr. Sci. (Chemistry), Leading Researcher Moscow, Russian Federation

I. Nikovskiy

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: igornikovskiy@mail.ru
ORCID iD: 0000-0001-9594-823X
PhD in Chemistry, Researcher Moscow, Russian Federation

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