Oxovanadium(IV) Complexes with Pyridinedicarboxylate Anions and Terpyridine: Synthesis, Structure, and EPR Spectra

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Abstract

The reactions of oxovanadium(IV) sulfate with potassium salts of 2,3-, 2,4-, 2,5-, 3,4-, and 3,5-pyridinedicarboxylic acids (PdcH2) and 2,2’:6’,2’’-terpyridine (Terpy) resulted in the formation of mononuclear heteroleptic complexes [VO(2,3-Pdc)(Terpy)] : 7H2O (I), [VO(2,4-Pdc)(Terpy)] : 5H2O (II), [VO(2,5-Pdc)(Terpy)] : 3H2O (III), [VO(3,4-Pdc)(Terpy)(H2O)] : 4H2O (IV), [VO(3,5-Pdc)(Terpy)(H2O)] : 7H2O (V) и [VO(3,5-PdcH)(Terpy)(H2O)](3,5-PdcH) : 2H2O (VI), respectively. The structures of compounds I–VI were determined by single-crystal X-ray diffraction (CCDC nos. 2326828 (I), 2326829 (II), 2326830 (III), 2326831 (IV), 2326832 (V), 2440463 (VI)). In the structures of I–III, the acid dianions act as chelating ligands via the pyridine N atom and the O atom of one carboxyl group, while in compounds IV–VI, the acid anion is coordinated in the monodentate fashion. In the crystal packing of compounds I–III, intermolecular π–π-interactions between the heteroatomatic moieties of N-donor ligands are present, while in complexes IV and V, the intermolecular π–π-interactions involve also the pyridyl rings of dicarboxylate anions. Polycrystalline samples and solutions of complexes III and IV were characterized by EPR spectroscopy.

About the authors

E. S Bazhina

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: bazhina@igic.ras.ru
ORCID iD: 0000-0003-4722-0599
PhD in Chemistry, Senior Researcher Moscow, Russian Federation

M. A Shmelev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: shmelevma@yandex.ru
ORCID iD: 0000-0002-7345-6856
PhD in Chemistry, Researcher Moscow, Russian Federation

N. V Gogoleva

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: gogolevanv@inbox.ru
ORCID iD: 0000-0002-3490-2833
PhD in Chemistry, Senior Researcher Moscow, Russian Federation

E. A Ugolkova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: tipperiri@yandex.ru
ORCID iD: 0000-0001-8192-7200
PhD in Physics and Mathematics, Senior Researcher Moscow, Russian Federation

N. N Efimov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nnefimov@yandex.ru
ORCID iD: 0000-0003-4651-7948
PhD in Chemistry, Leading Researcher Moscow, Russian Federation

M. A Kiskin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: mkiskin@igic.ras.ru
ORCID iD: 0000-0002-8782-1308
Dr. Sci. in Chemistry, Professor of the Russian Academy of Sciences, Leading Researcher Moscow, Russian Federation

I. L Eremenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ilerem@igic.ras.ru
ORCID iD: 0000-0001-6861-1404
Dr. Sci. in Chemistry, Full Member of the Russian Academy of Sciences, Head of Laboratory, Chief Researcher Moscow, Russian Federation

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