DIRECT ELEMENTAL ANALYSIS OF WINES BY MICROWAVE INDUCED PLASMA ATOMIC EMISSION SPECTROMETRY AND INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

Methods for the direct analysis of table wines by microwave induced plasma atomic emission spectrometry (MIP-AES) and inductively coupled plasma atomic emission spectrometry (ICP-AES) using matrix matching are presented. K, Na, Ca, Mg, B, Si, Al, Fe, Cu, Mn, Ba, Sr, Li, Zn are quantitatively determined from one dilution with an error of no more than 10% (n = 2). The range of constancy of analytical signals was determined when varying the concentrations of potassium, alcohol, and sucrose in MIP-AES analysis. It was shown that there is no decrease in the background signal when replacing nitrogen with air in the auxiliary flow, and that analytical characteristics improve when using yttrium as an internal standard in MIP-AES. The results were confirmed by capillary zone electrophoresis, the spiking method, and comparison of ICP-AES and MIP-AES analysis results.

About the authors

V. A Trunova

VMK-Optoelektronika

Novosibirsk, Russia

E. V Polyakova

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: e_polyak@niic.nsc.ru
Novosibirsk, Russia

O. V Komin

Institute of Automation and Electrometry, Siberian Branch of the Russian Academy of Sciences

Novosibirsk, Russia

O. V Pelipasov

Institute of Automation and Electrometry, Siberian Branch of the Russian Academy of Sciences

Novosibirsk, Russia

E. A Slastya

All-Russian National Scientific Research Institute of Viticulture and Winemaking "Magarach" of the National Research Center "Kurchatov Institute"

Yalta, Russia

N. S Anikina

All-Russian National Scientific Research Institute of Viticulture and Winemaking "Magarach" of the National Research Center "Kurchatov Institute"

Yalta, Russia

V. K Trefilov

All-Russian National Scientific Research Institute of Viticulture and Winemaking "Magarach" of the National Research Center "Kurchatov Institute"

Yalta, Russia

References

  1. Fontoura B.M., Cora Jofré F., Williams T., Savio M., Donati G.L., Nóbrega J.A. Is MIP-OES a suitable alternative to ICP-OES for trace element analysis? // J. Anal. At. Spectrom. 2022. V. 37. P. 966.
  2. Williams C.B., Amais R.S., Fontoura B.M., Jones B.T., Nóbrega J.A., Donati G.L. Recent developments in microwave-induced plasma optical emission spectrometry and applications of a commercial Hammer-cavity instrument // Trends Anal. Chem. 2019. V. 116. P. 151.
  3. Muller A., Pogebon D., Dressler V. L. Advances of nitrogen microwave plasma for optical emission spectrometry and applications in elemental analysis: A review // J. Anal. At. Spectrom. 2020. V. 35. P. 2113.
  4. Balaram V. Microwave plasma atomic emission spectrometry (MP-AES) and its applications – A critical review // Microchem. J. 2020. V. 159. Article 105483.
  5. Pelipasov O.V., Polyakova E.V. Matrix effects in atmospheric pressure nitrogen microwave induced plasma optical emission spectrometry // J. Anal. At. Spectrom. 2020. V. 35. P. 1389.
  6. Polyakova E.V., Pelipasov O.V. Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry // Spectrochim. Acta B. 2020. V. 173. Article 105988.
  7. Serrano R., Grindlay G., Gras L., Mora J. Microwave-sustained inductively coupled atmospheric-pressure plasma (MICAP) for the elemental analysis of complex matrix samples // Talanta. 2024. V. 271. Article 125666.
  8. Wiltsche H., Wolfgang M. Metits of microwave plasmas for optical emission spectrometry – characterization of an axially viewed microwave-sustained, inductively coupled, atmospheric-pressure plasma (MICAP) // J. Anal. At.Spectrom. 2020. V. 35. P. 236.
  9. Serrano R., Grindlay G., Gras L., Mora J. Evaluation of calcium-, carbon- and sulfur-based non-spectral interferences in high-power MIP-OES: Comparison with ICP-OES // J. Anal. At. Spectrom. 2019. V. 34. P. 1611.
  10. Cruz T.L.E., Esperanza M. G., Wrobel K., Barrientos E.Y., Aguilar F.J.A., Wrobel K. Determination of major and minor elements in Mexican red wines by microwave-induced plasma optical emission spectrometry, evaluating different calibration methods and exploring potential of the obtained data in the assessment of wine provenance // Spectrochim. Acta B. 2020. V. 164. Article 105754.
  11. Jung M.Y., Kang J.H., Choi Y.S., Lee D.Y., Lee J.Y., Park J.S. Analytical features of microwave plasma-atomic emission spectrometry (MP-AES) for the quantitation of manganese (Mn) in wild grape (Vitis coignetiae) red wines: Comparison with inductively coupled plasma-optical emission spectrometry (ICP-OES) // Food Chem. 2019. V. 274. P. 20.
  12. Carneiro C.N., de S. Dias F. Multiple response optimization of ultrasound-assisted procedure for multi-element determination in Brazilian wine samples by microwave-induced plasma optical emission spectrometry // Microchem. J. 2021. V. 171. Article 106857.
  13. Carneiro C.N., Gomez F.J.V., Spisso A., Silva M.F., Santos J.L.O., de S. Dias F. Exploratory analysis of South American wines using artificial intelligence // Biol. Trace Element Res. 2023. V. 201. P. 4590.
  14. Nelson J., Hopfer H., Gilleland G., Cultherson D., Boulton R., Ebeler S.E. Elemental profiling of Malbec wines under controlled conditions using microwave plasma-atomic emission spectroscopy // Am. J. Enol. Vitic. 2015. V. 66. P. 373.
  15. Karlsson S., Sjöberg V., Ogar A. Comparison of MPAES and ICP-MS for analysis of principal and selected trace elements in nitric acid digests of sunflower (Helianthus annuus) // Talanta. 2015. V. 135. P. 124.
  16. Pan Х.-D., Tang J., Chen Q., Wu P.-G., Ha J.-L. Evaluation of direct sampling method for trace elements analysis in Chinese rice wine by ICP–OES // Eur. Food Res. Technol. 2013. V. 236. P. 531.
  17. Лесю М., Abollino O., Bruzzontii M.C., Mentasti E., Sarzanini C., Malandrino M. Determination of metals in wine with atomic spectroscopy (flame-AAS, GF-AAS and ICP-AES); A review // Food Addit. Contam. 2002. V. 19. № 2. P. 126.
  18. Eschmauer H., Jakob L., Metefer H., Neeb R. Use and limitations of ICP-OES in wine analysis // Mikrochim. Acta. 1989. V. 3. P. 291.
  19. Thiel G., Danzer K. Direct analysis of mineral components in wine by inductively coupled plasma optical emission spectrometry (ICP-OES) // Fresenius J. Anal. Chem. 1997. V. 357. P. 553.
  20. Lara R., Cerutti S., Salonia J.A., Olsina R.A., Martinez L.D. Trace element determination of Argentine wines using ETAAS and USN-ICP-OES // Food Chem. Toxicol. 2005. V. 43. P. 293.
  21. Moreno I.M., González-Weller D., Gutierrez V., Marino M., Camelón A.M., González A.G., Hardisson A. Determination of Al, Ba, Ca, Cu, Fe, K, Mg, Mn, Na, Sr and Zn in red wine samples by inductively coupled plasma optical emission spectroscopy: Evaluation of preliminary sample treatments // Microchem. J. 2008. V. 88. P. 56.
  22. Szentmihályi K., Csikusnádi-Kiss G.A., Keszler A., Kótaí L., Candesias M., Bronze M.R., Boas L.V., Spauger I., Forgács E. Method development for measurement of elements in hungarian red wines by inductively coupled plasma optical emission spectrometry (ICP-OES) // Acta Alimentaria. 2000. V. 29. P. 105.
  23. Ivanova-Petropulos V., Wiltsche H., Stafilov T., Stefova M., Motter H., Lankmayr E. Multielement analysis of macedonian wines by inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES) for their classification // Macedonian J. Chem. Chem. Eng. 2013. V. 32. P. 265.
  24. Ziola-Frankowska A., Frankowski M. Determination of metals and metalloids in wine using inductively coupled plasma optical emission spectrometry and mini-torch // Food Anal. Methods. 2017. V. 10. P. 180.
  25. Rodrigues N.P., Rodrigues E., Celso P.G., Kahnann A., Yamashita G. H., Anzanello M.J., Manfroi V., Hertz P.F. Discrimination of sparkling wines samples according to the country of origin by ICP-OES coupled with multivariate analysis // LWT – Food Sci. Technol. 2020. V. 131. Article 109760.
  26. Šelin V.S., Šala M., Drgan V. Multi-element analysis of wines by ICP-MS and ICP-OES and their classification according to geographical origin in Slovenia // Food Chem. 2014. V. 153. P. 414.
  27. Plotka-Wasyika J., Frankowski M., Simeonov V., Polkowska Z., Namić'snik J. Determination of metals content in wine samples by inductively coupled plasma-mass spectrometry // Molecules. 2018. V. 23. P. 2886.
  28. Serrano R., Antico E., Grindlay G., Gras L., Fontas C. Determination of elemental bioavailability in soils and sediments by microwave induced plasma optical emission spectrometry (MIP-OES): Matrix effects and calibration strategies // Talanta. 2022. V. 240. 123166.
  29. Komin O.V., Pelipasov O.V. Effect of Ar on parameters of nitrogen microwave-induced plasma optical emission spectrometry // Spectrochim. Acta B: At. Spectrosc. 2025. V. 223 Article 107084.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences